Water → Aluminum Chloride Hydrate Thiourea

HRID 1902817

Reaction equation

HRID 1902817 reaction equation
[OH2:1].O.O.O.O.O.[Cl-:7].[Al+3:8].[Cl-].[Cl-].[NH2:11][C:12]([NH2:14])=[S:13].O>>[OH2:1].[Cl-:7].[Al+3:8].[Cl-:7].[Cl-:7].[NH2:11][C:12]([NH2:14])=[S:13]

Participants

4

Reactant 3

HCID 962WaterHCID 2723790ThioureaHCID 9794789AlCl3.6H2O

Product 1

HCID 86738713Aluminum Chloride Hydrate Thiourea

Conditions

Temperature
72 °C

Procedure

In a 5 liter flask is placed 482.8 g. (2.0 mole) aluminum chloride hexahydrate and 1826.8 g. (24.0 moles) thiourea and shaken to mix. To this is added 2284 g. (127 moles) water and heated with stirring to 72° C. to obtain a clear, colorless solution. White crystals form upon cooling leaving a clear solution of pH 1.7 and a final weight of 4592 g.

Workup

  1. customIn a 5 liter flask is placed
  2. additionto mix
  3. additionTo this is added 2284 g
  4. customto obtain a clear, colorless solution
  5. customWhite crystals form
  6. temperatureupon cooling
  7. customleaving a clear solution of pH 1.7

Sources & evidence

ORD record
ord-92eb2987676b43159ef2fe9e790f12cd
Source dataset
uspto-grants-1982_12
Patent number
US04366096

Linked notes

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