Basic information
- Standard SMILES
O.O.O.O.O.O.[Al+3].[Cl-].[Cl-].[Cl-]- InChIKey
JGDITNMASUZKPW-UHFFFAOYSA-K- Molecular formula
- AlCl3H12O6
- Average molar mass
- 241.43 g/mol
- Monoisotopic mass
- 239.951485
Names & identifiers
- Preferred name
- AlCl3.6H2O
- IUPAC
- aluminum;trichloride;hexahydrate
- English name
- Aluminium chloride hexahydrate
- Molecular formula
- AlCl3H2O
- Molecular weight
- 151.35
Names & synonyms
Show more names
Database identifiers
- CAS
7784-13-6- PubChem CID
- 9794789
- DTXSID
DTXSID8036990- UNII
- 3CYT62D3GA
Properties
Computed structural properties
- Topological polar surface area
- 6 Ų
- Hydrogen bond donors
- 6
- Hydrogen bond acceptors
- 9
- Rotatable bonds
- 0
- Heavy atoms
- 10
- Formal charge
- 0
- Complexity
- 0
Physicochemical properties
- Melting point
- 100 °C · 100°C (dec.)
- Density
- 2.39 · 2.39
- vapor pressure
- 1 mm · 1 mm Hg ( 100 °C)
- storage temp.
- 15 °C · Store at +15°C to +25°C.
- solubility
- 0.5 g/10 · water: soluble0.5g/10 mL, clear, colorless
- form
- Solid
- Specific Gravity
- 2.398 · 2.398
- color
- White To Light Yellow
- Odor
- Odorless
- PH Range
- 2.5 · 2.5 - 3.5
- PH
- 2.5 · 2.5 (50g/l, H2O, 20℃)
- Water Solubility
- 477 g/L · 477 g/L (20 ºC)
- Sensitive
- Moisture Sensitive
- Merck
- 14 · 14,337
- Exposure limits
- 2 mg/m3 · NIOSH: TWA 2 mg/m3
- Stability
- Stable, but may decompose upon exposure to moist air or water. Incompatible with acids.Note that decomposition of the anhydrous product, possibly caused by moisture leaking into the container or being trapped within it, may cause a pressure rise in a sealed container, potentially leading to explosive rupture.
- InChI
- 1S/Al.3ClH.6H2O/h;3*1H;6*1H2/q+3;;;;;;;;;/p-3
- InChIKey
- JGDITNMASUZKPW-UHFFFAOYSA-K
- SMILES
- Cl[Al](Cl)Cl.O.O.O.O.O.O
- LogP
- -1.38 · -1.380 (est)
- CAS DataBase Reference
- 7784 · 7784-13-6(CAS DataBase Reference)
- FDA UNII
- 3 CYT62D3GA · 3CYT62D3GA
- UNSPSC Code
- 12352302 · 12352302
- NACRES
- 55 · NA.55
- Symbol(GHS)
- 5 · GHS05
- Signal word
- Danger
- Hazard statements
- 314 · H314
- Precautionary statements
- 260 · P260-P280-P301+P330+P331-P303+P361+P353-P304+P340+P310-P305+P351+P338
- target organs
- Lungs
- Hazard Codes
- Xi,C
- Risk Statements
- 36 · 36/37/38-34-36/38-52
- Safety Statements
- 26 · 26-45-36/37/39
- RIDADR
- 3260 · UN 3260 8/PG 3
- WGK Germany
- 1 · 1
- RTECS
- 530000 · BD0530000
- TSCA
- Yes
- HazardClass
- 8 · 8
- PackingGroup
- III
- HS Code
- 28273200 · 28273200
- Storage Class
- 6.1 C · 6.1C - Combustible acute toxic Cat.3toxic compounds or compounds which causing chronic effects
- Hazard Classifications
- 1 Skin · Eye Dam. 1Skin Corr. 1BSTOT RE 1
- Toxicity
- 50 orally · LD50 orally in Rabbit: 3311 mg/kg
- Limited Quantities
- 1 Kg · 1 Kg (2.2 lbs) (solid)
- Excepted Quantities
- Max Inner Pack (30g or 30ml) and Max Outer Pack (500g or 500ml)
Safety & regulation
Safety data
- wgk
- 1
- tsca
- Yes
- rtecs
- BD0530000
- ridadr
- UN 3260 8/PG 3
- hs_code
- 28273200
- Toxicity
- LD50 orally in Rabbit: 3311 mg/kg
- risk_code
- 36/37/38-34-36/38-52
- Signal word
- Danger
- Symbol(GHS)
- GHS05
- hazard_code
- Xi,C
- safety_code
- 26-45-36/37/39
- hazard_class
- 8
- Storage Class
- 6.1C - Combustible acute toxic Cat.3toxic compounds or compounds which causing chronic effects
- packing_group
- III
- target organs
- Lungs
- Hazard statements
- H314
- Limited Quantities
- 1 Kg (2.2 lbs) (solid)
- Excepted Quantities
- Max Inner Pack (30g or 30ml) and Max Outer Pack (500g or 500ml)
- Hazard Classifications
- Eye Dam. 1Skin Corr. 1BSTOT RE 1
- Precautionary statements
- P260-P280-P301+P330+P331-P303+P361+P353-P304+P340+P310-P305+P351+P338
Chemistry & industry
Applications
UsesThe Aluminium chloride hexahydrate is used in the preparation of deodorant and antiperspirant. Also, it is applied in textile finishing to improve the antistatic characteristics and flammability ratings of various textile materials. Commercially, it is sold as crystalline powder or as a 28% solution in water.
UsesThe anhydrous form suitable as an acid catalyst, especially in Friedel-Crafts type reactions; in cracking of petroleum; in manufacture of rubbers, lubricants. The hexahydrate form used in preserving wood; disinfecting stables, slaughterhouses, etc.; in deodorants and antiperspirant preparations; refining crude oil; dyeing fabrics; manufacture of parchment paper.
Usesin preserving wood, disinfecting stables, etc.; in deodorants and antiperspirant preparations; in refining crude oil, and dyeing fabrics; in dental ceramics; in topical astringents
UsesPharmaceutical preparations of aluminum chloride hexahydrate are used to treat hyperhidrosis, a condition involving excessive sweating. It is also employed in deodorants, antiperspirant preparations, dyeing fabrics, refining crude oil, textile finishing, manufacturing parchment paper, preserving the wood and disinfecting stables. It also finds use as a reagent in organic synthesis. Aluminum chloride hexahydrate is also useful in water treatment process, medicine and cosmetic products.
Preparation methods
PreparationAluminum chloride hexahydrate is prepared by dissolving Al(OH)3 in conc. HCl and passing gaseous HCl through the solution at 0°C. The precipitate is washed with diethyl ether and dried. Alternatively, it is prepared by hydrolyzing anhydrous AlCl3 in cold dilute HCl.
Upstream & downstream products
Upstream raw materials
Downstream products
Suppliers50 total
Additional notes
DefinitionChEBI: Aluminium trichloride hexahydrate is a hydrate. It contains an aluminium trichloride.
Related reactions
Linked notes
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