Pyrrole-2-carboxaldehyde → 1,4,7-Tris(pyrrole-2ylmethyl)-1,4,7-triazacyclononane

HRID 1935360

Reaction equation

HRID 1935360 reaction equation
[NH:1]1[CH2:9][CH2:8][NH:7][CH2:6][CH2:5][NH:4][CH2:3][CH2:2]1.[NH:10]1[CH:14]=[CH:13][CH:12]=[C:11]1[CH:15]=O>[H][H].O=[Pt]=O>[NH:10]1[CH:14]=[CH:13][CH:12]=[C:11]1[CH2:15][N:1]1[CH2:9][CH2:8][N:7]([CH2:15][C:11]2[NH:10][CH:14]=[CH:13][CH:12]=2)[CH2:6][CH2:5][N:4]([CH2:15][C:11]2[NH:10][CH:14]=[CH:13][CH:12]=2)[CH2:3][CH2:2]1

Participants

4

Reactant 2

HCID 13854Pyrrole-2-carboxaldehydeHCID 1883181,4,7-Triazacyclononane

Product 1

HCID 224980961,4,7-Tris(pyrrole-2ylmethyl)-1,4,7-triazacyclononane

Reagents, catalysts & solvents 1

HCID 178506448HCID 178506448, compoundCatalyst

Procedure

From 1,4,7-triazacyclononane (1.1.3), pyrrole-2-carboxaldehyde (commercially available) and H2/PtO2.

Sources & evidence

ORD record
ord-033204856c294ba59f13dd168771a75a
Source dataset
uspto-grants-2002_05
Patent number
US06387891B2

Linked notes

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