Trichlorosilane → Silane, trichloro[(trimethylsilyl)methyl]-
Reaction equation
Cl[CH2:2][Si:3]([CH3:6])([CH3:5])[CH3:4].[Cl:7][SiH:8]([Cl:10])[Cl:9]>[Cl-].C([P+](C1C=CC=CC=1)(C1C=CC=CC=1)C1C=CC=CC=1)C1C=CC=CC=1>[Cl:7][Si:8]([Cl:10])([Cl:9])[CH2:2][Si:3]([CH3:6])([CH3:5])[CH3:4]Participants
4
Reactant 2
Product 1
Reagents, catalysts & solvents 1
Procedure
In the same apparatus and procedure as Example 1 above, 0.29 g (0.75 mmol) of benyltriphenylphosphonium chloride, 0.92 g (7.5 mmol) of (chloromethyl)trimethylsilane, and 3.05 g (22.5 mmol ) of trichlorosilane were reacted at 150° C. for 10 hrs. The resulting mixture was distilled to give 1.20 g of 1,1,1-trichloro-3,3-dimethyl-1,3-disilabutane (yield; 72%).
Workup
- distillationThe resulting mixture was distilled
Sources & evidence
- ORD record
- ord-60b1ea18e1794627a2ae7b33b6fbf689
- Source dataset
- uspto-grants-2002_05
- Patent number
- US06392077B1
Reaction notes
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