Hydrochloric Acid → Barbital

Reaction equation

[CH3:1][CH2:2][C:3]1([CH2:12][CH3:13])[C:9](=[O:10])[N:8]=[C:7]([O-:11])[NH:6][C:4]1=[O:5].[Na+].[N-]=[N+]=[N-].[Na+].Cl>>[CH3:1][CH2:2][C:3]1([CH2:12][CH3:13])[C:4](=[O:5])[NH:6][C:7](=[O:11])[NH:8][C:9]1=[O:10]

Participants

Reactant 3

HCID 313Hydrochloric Acid

HCID 33557Sodium Azide

HCID 23681217Barbital Sodium

Product 1

HCID 2294Barbital

Procedure

Sodium Barbitone was made up to a final concentration of 0.07M together with 0.1% (w/v) sodium azide. The pH of this solution was adjusted to 8.4 with concentrated hydrochloric acid before making up to the final volume.

Sources & evidence

ORD record: ord-5f09ac7ad696411c896681046e4b19d6
Source dataset: uspto-grants-1985_04
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US04508830

Reaction notes

Loading…