Dimethyl Sulfoxide → 1h-Indazole-1-carboxylic acid,5-(azidomethyl)-3-(3-fluorophenyl)-,1,1-dimethylethyl ester

HRID 204841

Reaction equation

HRID 204841 reaction equation
[CH3:30][CH2:31][O:32][CH2:33][CH3:34].[CH3:35][S:36](=[O:37])[CH3:38].[Cl:1][CH2:2][c:3]1[cH:4][c:5]2[c:6](-[c:19]3[cH:20][c:21]([F:25])[cH:22][cH:23][cH:24]3)[n:7][n:8]([C:12](=[O:13])[O:14][C:15]([CH3:16])([CH3:17])[CH3:18])[c:9]2[cH:10][cH:11]1.[N-:27]=[N+:28]=[N-:29].[Na+:26]>>[CH2:2]([c:3]1[cH:4][c:5]2[c:6](-[c:19]3[cH:20][c:21]([F:25])[cH:22][cH:23][cH:24]3)[n:7][n:8]([C:12](=[O:13])[O:14][C:15]([CH3:16])([CH3:17])[CH3:18])[c:9]2[cH:10][cH:11]1)[N:27]=[N+:28]=[N-:29]

Participants

6

Reactant 5

HCID 679Dimethyl SulfoxideHCID 923Sodium ionHCID 3283Diethyl EtherHCID 33558AzideHCID 222606161h-Indazole-1-carboxylic acid,5-(chloromethyl)-3-(3-fluorophenyl)-,1,1-dimethylethyl ester

Product 1

HCID 222608731h-Indazole-1-carboxylic acid,5-(azidomethyl)-3-(3-fluorophenyl)-,1,1-dimethylethyl ester

Sources & evidence

ORD record
ord-4d3bb6fa820042b3a8b70415b4f4fdc3
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (6/10)

Linked notes

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