2-(5-Oxiranyl-furan-2-yl)-[1,3]dioxolane → (5-[1,3]Dioxolan-2-yl-furan-2-yl)-acetaldehyde

HRID 2080112

Reaction equation

HRID 2080112 reaction equation
[O:1]1[CH2:3][CH:2]1[C:4]1[O:8][C:7]([CH:9]2[O:13][CH2:12][CH2:11][O:10]2)=[CH:6][CH:5]=1>C(OCC)(=O)C>[O:10]1[CH2:11][CH2:12][O:13][CH:9]1[C:7]1[O:8][C:4]([CH2:2][CH:3]=[O:1])=[CH:5][CH:6]=1

Participants

3

Reactant 1

HCID 231307652-(5-Oxiranyl-furan-2-yl)-[1,3]dioxolane

Product 1

HCID 86042298(5-[1,3]Dioxolan-2-yl-furan-2-yl)-acetaldehydeYield 69.8%

Reagents, catalysts & solvents 1

HCID 8857Ethyl AcetateSolvent

Procedure

The resulting 2-(5-oxiranyl-furan-2-yl)-[1,3]dioxolane (2.25 g) and silica gel (5.00 g) were suspended in ethyl acetate (40 mL), and the solution was stirred for 6.5 hours at room temperature. The reaction solution was filtered, then, the filtrate was evaporated in vacuo, and (5-[1,3]dioxolan-2-yl-furan-2-yl)-acetaldehyde (1.57 g) was obtained as a yellow oil.

Workup

  1. filtrationThe reaction solution was filtered
  2. customthe filtrate was evaporated in vacuo

Sources & evidence

ORD record
ord-e5c89323eebe410eaa5f3bbf613666b1
Source dataset
uspto-grants-2011_04
Patent number
US07932272B2

Linked notes

Loading…