Butyl nitrite → HCID 76608724, compound

Reaction equation

[Br:1][C:2]1[CH:10]=[C:9]2[C:5]([CH2:6][CH2:7][C:8]2=[O:11])=[CH:4][C:3]=1[O:12][CH3:13].C([O:18][N:19]=O)CCC>>[Br:1][C:2]1[CH:10]=[C:9]2[C:5]([CH2:6][C:7](=[N:19][OH:18])[C:8]2=[O:11])=[CH:4][C:3]=1[O:12][CH3:13]

Participants

Reactant 2

HCID 10996Butyl nitrite

HCID 100602256-bromo-5-methoxy-2,3-dihydro-1H-inden-1-one

Product 1

HCID 76608724HCID 76608724, compound

Procedure

Similar procedure as described in example 9B was used, starting from 6-Bromo-5-methoxy-indan-1-one and n-butylnitrite to give 6-Bromo-5-methoxy-indan-1,2-dione 2-oxime. LC-MS: m/e 270 (MH+).

Sources & evidence

ORD record: ord-1ee7e2044973416486044febd624fca5
Source dataset: uspto-grants-2009_08
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US07572809B2

Reaction notes

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