Ammonia → Ammonia

HRID 2118263

Reaction equation

HRID 2118263 reaction equation
[NH3:1].CO[CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH3:11]>>[NH3:1].[CH3:11][CH2:10][CH2:9][CH2:8][CH2:7][CH2:6][CH:5]=[CH2:4]

Participants

4

Procedure

Ammonia gas was slowly bubbled through 1-methoxyoctane (50 mL) for 1 hour to form a saturated ammonia solution in 1-methoxyoctane. Analysis of ammonia in methoxyoctane indicated that the solution was saturated after 30 minutes of bubbling (15 min, 2372 mg NH3/L; 30 min, 3016 mg NH3/L; 60 min, 2924 mg NH3/L; 90 min, 3294 mg NH3/L). The NH3 saturated methoxyoctane solution was used as feed to the cracking reactor. The data are presented in Table 3. (NH3 helps to give higher conversion while maintaining high octene-1 selectivity.)

Workup

  1. customof bubbling (15 min, 2372 mg NH3/L; 30 min, 3016 mg NH3/L; 60 min, 2924 mg NH3/L; 90 min, 3294 mg NH3/L)

Sources & evidence

ORD record
ord-3779267464b54ace9e7db4494a218cfc
Source dataset
uspto-grants-2008_10
Patent number
US07442845B2

Linked notes

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