Dimethyl Sulfoxide → Methyl 2-[(4-bromophenyl)sulfonyl]benzoate

Reaction equation

[Br:14][c:15]1[cH:16][cH:17][c:18]([S:21](=[O:22])[O-:23])[cH:19][cH:20]1.[Br:1][c:2]1[c:3]([C:4](=[O:5])[O:6][CH3:7])[cH:8][cH:9][cH:10][cH:11]1.[CH3:27][S:28]([CH3:29])=[O:30].[Cu:25][I:26].[Na+:24].[OH2:12].[OH2:13]>>[c:2]1([S:21]([c:18]2[cH:17][cH:16][c:15]([Br:14])[cH:20][cH:19]2)(=[O:22])=[O:23])[c:3]([C:4](=[O:5])[O:6][CH3:7])[cH:8][cH:9][cH:10][cH:11]1

Participants

Reactant 6

HCID 679Dimethyl Sulfoxide

HCID 923Sodium Ion

HCID 962Water2×

HCID 11894Methyl 2-bromobenzoate

HCID 24350Copper(1+) iodide; Copper(I) iodide; Cuprous iodide; Cuprous iodide (CuI)

HCID 3767219CID 3767219

Product 1

HCID 21099525Methyl 2-[(4-bromophenyl)sulfonyl]benzoate

Sources & evidence

ORD record: ord-c2cc559ceb3e4c7097f2e38953789b30
Source dataset: Training data from https://doi.org/10.1039/C8SC04228D (6/10)
DOI: 10.1039/C8SC04228D

Reaction notes

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