Sulfuric Acid → Potassium disorbate

HRID 2163147

Reaction equation

HRID 2163147 reaction equation
S(=O)(=O)(O)O.[C:6]([OH:13])(=[O:12])/[CH:7]=[CH:8]/[CH:9]=[CH:10]/[CH3:11].[OH-].[K+:15]>[Fe].O>[C:6]([O-:13])(=[O:12])/[CH:7]=[CH:8]/[CH:9]=[CH:10]/[CH3:11].[C:6]([O-:13])(=[O:12])/[CH:7]=[CH:8]/[CH:9]=[CH:10]/[CH3:11].[K+:15].[K+:15]

Participants

6

Reactant 3

HCID 1118Sulfuric AcidHCID 14797Potassium HydroxideHCID 643460Sorbic Acid

Product 1

HCID 18759366Potassium disorbate

Reagents, catalysts & solvents 2

HCID 23925IronCatalystHCID 962WaterSolvent

Procedure

25 l of active coal (based on pit coal, granulation: 2-4 mm) which had been freed from iron by sulfuric acid (at 1%) and subsequently neutralized by washing with water, were charged into a tube having a length of 10 m and being equipped with a heating jacket (nominal size: 50 mm) in such a way, that no gas bubbles are formed while charging. At a temperature of from 75°-85° C. a solution prepared at 80° C. of 56 parts by weight of sorbic acid (at 89%), 15.8 parts by weight of potassium hydroxide (scales, at 90%) and of 35.2 parts by weight of water is pumped through this column under a nitrogen atmosphere from the bottom to the top at an hourly rate of 2.5 kg. The purified solution is filtered while still hot and cooled to room temperature within the next 4 hours. The crystallization product is removed by centrifugation and dried in vacuo at 50° C. 1.08 kg of potassium disorbate are obtained per hour, which contains from 0.6-0.7 weight % of potassium sorbate more than the stoichiometric quantity would stand for. The yield is from 98-99%, calculated on the sorbic acid (at 100%). The mother liquor is re-used after dissolution of 22.4 parts by weight of crude sorbic acid and of 5.8 parts by weight of potassium hydroxide in 100 parts by weight of mother liquor.

Workup

  1. washby washing with water
  2. additionwere charged into a tube
  3. custombeing equipped with a heating jacket (nominal size: 50 mm) in such a way
  4. customthat no gas bubbles are formed
  5. filtrationThe purified solution is filtered while still hot and
  6. customThe crystallization product is removed by centrifugation
  7. customdried in vacuo at 50° C

Sources & evidence

ORD record
ord-e70d5d829a044c83b3fed80e9f0ae4d8
Source dataset
uspto-grants-1979_01
Patent number
US04132733

Linked notes

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