3,7-Dimethylocta-2,6-Dienal → Citronellal

HRID 2174402

Reaction equation

[CH3:1][C:2](=[CH:4][CH2:5][CH2:6][C:7](=[CH:9][CH:10]=[O:11])[CH3:8])[CH3:3].CC(=CCC/C(=C/C=O)/C)C.CC(=CCC/C(=C\C=O)/C)C>>[CH3:1][C:2](=[CH:4][CH2:5][CH2:6][CH:7]([CH2:9][CH:10]=[O:11])[CH3:8])[CH3:3]

Participants

Reactant 3

HCID 88433,7-Dimethylocta-2,6-Dienal

HCID 638011Citral

HCID 643779Neral

Product 1

HCID 7794Citronellal

Procedure

A-4) asymmetrically hydrogenating citral containing geranial and neral at a molar ratio of from 90:10 to 10:90 to thereby obtain an optically active citronellal,

Sources & evidence

ORD record: ord-41cf53917ec74432abc1d8008f01f722
Source dataset: uspto-grants-2015_06
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US09061959B2

Linked notes

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