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Sulfuric acid magnesium salt (1:1) → Magnesium Sulfate Heptahydrate

HRID 217558
Notes
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Reaction equation

HRID 217558 reaction equation
[S:1]([O-:5])([O-:4])(=[O:3])=[O:2].[Mg+2:6]>O>[OH2:2].[OH2:2].[OH2:2].[OH2:2].[OH2:2].[OH2:2].[OH2:2].[S:1]([O-:5])([O-:4])(=[O:3])=[O:2].[Mg+2:6]
ParticipantsProcedureSources & evidenceReaction notes

Participants

3

Reactant 1

HCID 24083Sulfuric acid magnesium salt (1:1)

Product 1

HCID 24843Magnesium Sulfate Heptahydrate

Reagents, catalysts & solvents 1

HCID 962WaterSolvent2×

Procedure

The results described above would not have been expected because sodium sulfate absorbs more water per unit weight than magnesium sulfate. One kilogram of sodium sulfate (7.04 moles) absorbs 70.4 moles of water to form sodium sulfate decahydrate, or 1.27 kg water/kg sodium sulfate. One kilogram of magnesium sulfate (8.31 moles) absorbs 58.15 moles of water to form magnesium sulfate heptahydrate, or only 1.05 kg water/kg magnesium sulfate. Therefore, there would have been no reason to expect aqueous biocide compositions to form solids with much smaller amounts of magnesium sulfate, relative to sodium sulfate.

Sources & evidence

ORD record
On this pageParticipantsProcedureSources & evidenceReaction notes
ord-dabf938186674d4981a2a5a93c051821
Source dataset
uspto-grants-2012_06
DOI
10.6084/m9.figshare.5104873.v1
Patent number
US08197836B2

Reaction notes

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