Propylene Oxide → Sodium silicate methyl methacrylate propylene oxide

HRID 223426

Reaction equation

HRID 223426 reaction equation
[Si:1]([O-:5])([O-:4])([O-:3])[O-:2].[Na+:6].[Na+].[Na+].[Na+].[C:10]([O:15][CH3:16])(=[O:14])[C:11]([CH3:13])=[CH2:12].[CH2:17]1[O:20][CH:18]1[CH3:19].C1(=O)OC(=O)C2=CC=CC=C12.[OH-].[Na+].C(OOC(=O)C1C=CC=CC=1)(=O)C1C=CC=CC=1>>[Si:1]([O-:5])([O-:4])([O-:3])[O-:2].[Na+:6].[Na+:6].[Na+:6].[Na+:6].[C:10]([O:15][CH3:16])(=[O:14])[C:11]([CH3:13])=[CH2:12].[CH2:17]1[O:20][CH:18]1[CH3:19]

Participants

7

Reactant 6

HCID 6378Propylene OxideHCID 6658Methyl MethacrylateHCID 6811Phthalic AnhydrideHCID 7187Benzoyl PeroxideHCID 14798Sodium HydroxideHCID 26051Sodium orthosilicate

Product 1

HCID 86738390Sodium silicate methyl methacrylate propylene oxide

Procedure

About 50 parts by weight of an aqueous sodium silicate solution containing about 10% Na2O and 25% SiO2 by weight, 25 parts by weight of methyl methacrylate, 10 parts by weight of propylene oxide, 2 parts by weight of phthalic anhydride, 5 parts by weight of sodium hydroxide and 0.5 parts by weight of benzoyl peroxide are thoroughly mixed thereby producing an emulsion. The mixture is reacted at ambient temperature and pressure for 1 to 24 hours thereby producing a poly(sodium silicate-methyl methacrylate-propylene oxide) copolymer emulsion.

Workup

  1. additionare thoroughly mixed
  2. customthereby producing an emulsion
  3. customThe mixture is reacted at ambient temperature

Sources & evidence

ORD record
ord-6eb2507fcd6a407a86ced2665dfdb27e
Source dataset
uspto-grants-1982_10
Patent number
US04353999

Linked notes

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