Sodium Dimethyldithiocarbamate → Ziram

HRID 223766

Reaction equation

HRID 223766 reaction equation
[CH3:1][N:2]([C:4]([S-:6])=[S:5])[CH3:3].[Na+].[Cl-].[Cl-].[Zn+2:10]>O>[CH3:1][N:2]([C:4]([S-:6])=[S:5])[CH3:3].[CH3:1][N:2]([C:4]([S-:6])=[S:5])[CH3:3].[Zn+2:10]

Participants

4

Reactant 2

HCID 560256Sodium Dimethyldithiocarbamate2×HCID 3007855Zincchloride

Product 1

HCID 8722Ziram

Reagents, catalysts & solvents 1

HCID 962WaterSolvent

Procedure

Sodium dimethyl dithiocarbamate (75.2 g, 0.66 mole) is dissolved in 100 ml H2O. A ZnCl2 solution (45.4 g, 0.33 mole dissolved in 300 ml H2O) is added to the sodium dimethyl dithiocarbamate solution. Immediately, a white precipitate forms which is filtered and dried to give a quantitative yield of zinc dimethyl dithiocarbamate.

Workup

  1. filtrationImmediately, a white precipitate forms which is filtered
  2. customdried

Sources & evidence

ORD record
ord-8f902aa3dd244ca4a0b3712670d646a1
Source dataset
uspto-grants-1982_10
Patent number
US04356274

Linked notes

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