Hydrogen Sulfide → 1-Dodecanethiol

HRID 224537

Reaction equation

HRID 224537 reaction equation
[SH2:1].[CH3:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH:12]=[CH2:13]>COCCOCCOC>[CH2:13]([SH:1])[CH2:12][CH2:11][CH2:10][CH2:9][CH2:8][CH2:7][CH2:6][CH2:5][CH2:4][CH2:3][CH3:2]

Participants

4

Reactant 2

HCID 402Hydrogen SulfideHCID 81831-Dodecene

Product 1

HCID 81951-Dodecanethiol

Reagents, catalysts & solvents 1

HCID 8150DiglymeSolvent

Procedure

Under the conditions of Example 3, with an input of 38 liters per hour of hydrogen sulphide, 67.7 mmoles of dodecene-1 dissolved in diglyme at a concentration of 0.564 mole per liter were irradiated at 11° C. After 3 minutes of irradiation, 48.2 mmoles of n-dodecyl mercaptan were formed.

Workup

  1. customwere irradiated at 11° C
  2. customAfter 3 minutes of irradiation

Sources & evidence

ORD record
ord-b779b01eec7b4804ae0da5ef95b9639e
Source dataset
uspto-grants-1980_11
Patent number
US04233128

Linked notes

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