Ethylamine → (E)-N-(6,6-dimethyl-2-hepten-4-ynyl)-N-methyl-3-hydroxybenzylamine

HRID 2254425Notes

Reaction equation

HRID 2254425 reaction equation
C(N)C.C(N)CC.[CH3:8][C:9]([CH3:27])([CH3:26])[C:10]#[C:11]/[CH:12]=[CH:13]/[CH2:14][N:15]([CH2:18][C:19]1[CH:24]=[CH:23][CH:22]=[C:21]([OH:25])[CH:20]=1)[CH2:16]C.CC(C)(C)C#C/C=C/CN(CC1C=CC=C(O)C=1)CCC>>[CH3:8][C:9]([CH3:27])([CH3:26])[C:10]#[C:11]/[CH:12]=[CH:13]/[CH2:14][N:15]([CH2:18][C:19]1[CH:24]=[CH:23][CH:22]=[C:21]([OH:25])[CH:20]=1)[CH3:16]

Participants

5

Reactant 4

HCID 6341EthylamineHCID 7852PropylamineHCID 10445905(E)-N-(6,6-Dimethyl-2-hepten-4-ynyl)-N-ethyl-3-hydroxybenzylamineHCID 15290087(E)-N-(6,6-Dimethyl-2-hepten-4-ynyl)-N-propyl-3-hydroxybenzylamine

Product 1

HCID 19916986(E)-N-(6,6-dimethyl-2-hepten-4-ynyl)-N-methyl-3-hydroxybenzylamine

Procedure

When the same reaction as above is carried out using ethylamine or propylamine instead of methylamine, (E)-N-(6,6-dimethyl-2-hepten-4-ynyl)-N-ethyl-3-hydoxybenzylamine used in Examples 101 to 103 or (E)-N-(6,6-dimethyl-2-hepten-4-ynyl)-N-propyl-3-hydroxybenzylamine used in Examples 104 and 105 is obtained.

Workup

  1. customWhen the same reaction
  2. custom105 is obtained

Sources & evidence

ORD record
ord-0d560a57d2e248d19a3d39b2b871aac4
Source dataset
uspto-grants-1993_08
Patent number
US05234946

Reaction notes

Loading…