Dimethyl pyridine-3,5-dicarboxylate → 6-(5-Oxazolyl)-2-pyridinemethanol

HRID 2254457Notes

Reaction equation

HRID 2254457 reaction equation
[N:1]1[C:6]([C:7]([O:9]C)=O)=[CH:5][CH:4]=[CH:3][C:2]=1[C:11]([O:13][CH3:14])=O.[N:15]1C=C(C(OC)=O)C=C(C(OC)=O)[CH:16]=1>>[O:13]1[C:11]([C:2]2[N:1]=[C:6]([CH2:7][OH:9])[CH:5]=[CH:4][CH:3]=2)=[CH:16][N:15]=[CH:14]1

Participants

3

Reactant 2

HCID 78339Dimethyl pyridine-3,5-dicarboxylateHCID 79549Dimethyl pyridine-2,6-carboxylate

Product 1

HCID 197445026-(5-Oxazolyl)-2-pyridinemethanol

Procedure

When the same reaction as in Referential Example 39 is carried out using dimethyl pyridine-2,6-dicarboxylate instead of the starting dimethyl pyridine-3,5-dicarboxylate, 6-(5-oxazolyl)-2-pyridinemethanol is obtained.

Workup

  1. customWhen the same reaction as in Referential Example 39

Sources & evidence

ORD record
ord-4a260457f6a7431590bbe8c8ed13d51b
Source dataset
uspto-grants-1993_08
Patent number
US05234946

Reaction notes

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