Diethylaluminum chloride → 1-Octene

HRID 22577

Reaction equation

HRID 22577 reaction equation
[Al](Cl)([CH2:4][CH3:5])[CH2:2]C.[H][H].[CH3:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH3:15]>>[CH2:9]=[CH:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:4][CH3:5].[CH2:9]=[CH:10][CH2:11][CH2:12][CH2:13][CH2:14][CH:15]=[CH2:2]

Participants

5

Reactant 3

HCID 7277Diethylaluminum chlorideHCID 8900HeptaneHCID 178418361HCID 178418361, compound

Product 2

HCID 81251-OcteneHCID 194601,7-Octadiene

Procedure

A solution of 81.5 grams (0.966 mole) 1-octene and 5.61 grams (0.0509 mole) 1,7-octadiene (molar charge ratio 95:5) in 450 grams of heptane was polymerized with Et2AlCl (16 millimoles) and AATiCl3 (4 millimoles) at 50° C. for 10 hours. During the course of the reaction, hydrogen was bubbled through the reaction mixture. The conversion of the polymer was 52 percent, inherent viscosity was 1.9 dl/gram. The composition of monomers in the copolymer was 97:3 mole ratio from NMR analysis.

Workup

  1. customwas bubbled through the reaction mixture

Sources & evidence

ORD record
ord-87da2cd7a1004668b0b227c1ea33b62b
Source dataset
uspto-grants-1995_06
Patent number
US05428209

Linked notes

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