HuagongsheHuagongshe Chemistry Print Report · For research reference only
7-Chloro-2-methylquinoline → Dimethyl 5-(3-(2-(7-chloroquinolin-2-yl)ethenyl)phenyl)-4,6-dithianonanedioate
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 7-Chloro-2-methylquinoline | HCID 138395 | — |
| Reactant | Dimethyl 3,3'-(((3-formylphenyl)methylene)bis(sulfanediyl))dipropanoate | HCID 10021188 | — |
| Solvent | Acetic Anhydride | HCID 7918 | — |
| Product | Dimethyl 5-(3-(2-(7-chloroquinolin-2-yl)ethenyl)phenyl)-4,6-dithianonanedioate | HCID 53731421 | — |
Reaction Steps
A solution of aldehyde (Step 1) (5.2 g) and 7-chloroquinaldine were heated in 45 ml acetic anhydride for 48 hours. The reaction mixture was evaporated. Flash chromatography of the residue using 5% ethylacetate in hexane afforded the title compound.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05428171 |
| Source dataset | uspto-grants-1995_06 |
| ORD ID | ord-cfa2eb7e011a42859db8e0347809ca74 |
| Source note | uspto-grants-1995_06 |