Hydrofluoric Acid → HCID 11412739, compound

HRID 231624

Reaction equation

[O:1]=[CH:2][C@H:3]([C@H:5]([C@@H:7]([C@@H:9]([CH2:11][OH:12])[OH:10])[OH:8])[OH:6])O.[FH:13]>>[C@H:11]1([F:13])[O:12][C@H:3]([CH2:2][OH:1])[C@@H:5]([OH:6])[C@H:7]([OH:8])[C@@H:9]1[OH:10]

Participants

Reactant 2

HCID 14917Hydrofluoric Acid

HCID 161658Demannose

Product 1

HCID 11412739HCID 11412739, compoundYield 98.9%

Procedure

In the same way as described in Example 3, 1 g of D-mannose was reacted with 10 g of hydrogen fluoride. About 1 g of α-D-mannosyl fluoride ws isolated and identified by comparison with authentic material (cf. Barnett 35 al., loc. cit. in Example 3).

Sources & evidence

ORD record: ord-b4509466327d42939bf9fde5c84f8220
Source dataset: uspto-grants-1989_07
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US04847372

Linked notes

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