Diethyl Oxalate → Ethyl 2-oxo-2-(10-oxotricyclo[6.2.2.02,7]dodeca-2,4,6-trien-9-yl)acetate

HRID 2321790

Reaction equation

HRID 2321790 reaction equation
[C:54]([C:55](=[O:56])[O:57][CH2:58][CH3:59])(=[O:60])[O:61][CH2:62][CH3:63].[CH3:40][SiH:41]([CH3:42])[N:43]([CH3:44])[Si:45]([CH3:46])([CH3:47])[CH3:48].[CH3:49][CH2:50][CH2:51][CH2:52][Li:53].[CH:27]12[c:28]3[cH:29][cH:30][cH:31][cH:32][c:33]3[CH:34]([C:35](=[O:37])[CH2:36]1)[CH2:38][CH2:39]2.[Cl:1][c:2]1[cH:3][c:4]([Cl:5])[cH:6][cH:7][c:8]1-[n:9]1[n:10][c:11]([C:12]([OH:13])=[O:14])[c:15]2[c:26]1[CH:19]1[CH2:18][CH2:17][CH:16]2[c:21]2[c:20]1[cH:25][cH:24][cH:23][cH:22]2>>[CH:27]12[c:28]3[cH:29][cH:30][cH:31][cH:32][c:33]3[CH:34]([C:35](=[O:37])[CH:36]1[C:54]([C:55](=[O:56])[O:57][CH2:58][CH3:59])=[O:60])[CH2:38][CH2:39]2

Participants

6

Reactant 5

HCID 7268Diethyl OxalateHCID 5825961,4-Ethanonaphthalen-2(1H)-one, 3,4-dihydro-HCID 589711N-dimethylsilyl-N-trimethylsilylmethanamineHCID 8662333710-(2,4-Dichlorophenyl)-10,11-diazatetracyclo[6.5.2.02,7.09,13]pentadeca-2,4,6,9(13),11-pentaene-12-carboxylic acidHCID 178418339Butyllithium

Product 1

HCID 67029310Ethyl 2-oxo-2-(10-oxotricyclo[6.2.2.02,7]dodeca-2,4,6-trien-9-yl)acetate

Sources & evidence

ORD record
ord-f596068aeb574e3a9c0bee365cae88a8
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (10/10)

Linked notes

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