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Methacrylic Acid → Iron(2+) methacrylate

HRID 2367663
Notes
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Reaction equation

HRID 2367663 reaction equation
[C:1]([OH:6])(=[O:5])[C:2]([CH3:4])=[CH2:3].[Fe:7].[N+]([O-])([O-])=O.[Fe+2].[N+]([O-])([O-])=O>O>[C:1]([O-:6])(=[O:5])[C:2]([CH3:4])=[CH2:3].[Fe+2:7].[C:1]([O-:6])(=[O:5])[C:2]([CH3:4])=[CH2:3]
ParticipantsProcedureSources & evidenceReaction notes

Participants

5

Reactant 3

HCID 4093Methacrylic AcidHCID 23925IronHCID 9815404Ferrous nitrate

Product 1

HCID 57356750Iron(2+) methacrylateYield 90%

Reagents, catalysts & solvents 1

HCID 962WaterSolvent

Procedure

For example, a method has been proposed, in which methacrylic acid, an alkaline metal and an iron salt such as iron nitrate are mixed in a solvent such as water, and iron methacrylate is produced by salt exchange (Patent Literature 1). Since this method has a difficulty in securely completing salt exchange, iron methacrylate is difficult to obtain in a high yield of 90% or higher. The method has further problems such as a reduction in purity due to contamination of iron methacrylate with impurities derived from nitric acid, and a rise in the cost because of necessity of filtration and drying processes. In the case where a hydroxyalkyl methacrylate is produced by using the prepared iron methacrylate as a catalyst, there are concern about problems, such as by-production of impurities, coloration and the like derived from nitric acid contained in the catalyst raw material.

Sources & evidence

ORD record
ord-faa126c2e6514023991d1dce018ad3e9
Source dataset
uspto-grants-2014_04
DOI
10.6084/m9.figshare.5104873.v1
Patent number
US08697899B2

Reaction notes

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On this pageParticipantsProcedureSources & evidenceReaction notes