Ammonium Hydroxide → 2-chloro-3,5-dinitrobenzamide

Reaction equation

[Cl:1][C:2]1[C:10]([N+:11]([O-:13])=[O:12])=[CH:9][C:8]([N+:14]([O-:16])=[O:15])=[CH:7][C:3]=1[C:4](Cl)=[O:5].[OH-].[NH4+:18]>>[Cl:1][C:2]1[C:10]([N+:11]([O-:13])=[O:12])=[CH:9][C:8]([N+:14]([O-:16])=[O:15])=[CH:7][C:3]=1[C:4]([NH2:18])=[O:5]

Participants

Reactant 2

HCID 14923Ammonium Hydroxide

HCID 12897330HCID 12897330, compound

Product 1

HCID 2356272-chloro-3,5-dinitrobenzamide

Procedure

A mixture of 37.0 gm. (0.14 mole) of 2-chloro-3,5-dinitrobenzoyl chloride and 100 ml. of concentrated ammonium hydroxide is placed in a mortar, ground for ten minutes and allowed to stand for one hour. The yellow precipitate is removed by filtration and washed with water. There is obtained 32.3 gm. (94%) of material melting at 181°-3°.

Workup

additionA mixture of 37.0 gm
customThe yellow precipitate is removed by filtration
washwashed with water
customThere is obtained 32.3 gm

Sources & evidence

ORD record: ord-41199570bbc44dddab7c5b164e41ca69
Source dataset: uspto-grants-1979_06
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US04159278

Reaction notes

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