m-Chloroperbenzoic acid → 3-methylsulfinyl-N'-sulfamoylpropanimidamide

HRID 2413345

Reaction equation

HRID 2413345 reaction equation
ClC1C=CC=C(C(OO)=[O:9])C=1.[S:12]([NH:16][C:17](=[NH:22])[CH2:18][CH2:19][S:20][CH3:21])(=[O:15])(=[O:14])[NH2:13]>C(Cl)(Cl)Cl.CO>[S:12]([NH:16][C:17](=[NH:22])[CH2:18][CH2:19][S:20]([CH3:21])=[O:9])(=[O:14])(=[O:15])[NH2:13]

Participants

5

Reactant 2

HCID 70297m-Chloroperbenzoic acidHCID 178503794HCID 178503794, compound

Product 1

HCID 1785046403-methylsulfinyl-N'-sulfamoylpropanimidamide

Reagents, catalysts & solvents 2

HCID 887MethanolSolventHCID 6212ChloroformSolvent

Procedure

A solution of commercial 80% pure m-chloroperbenzoic acid (5.4 g, 25 mmol) in chloroform (40 ml) was added dropwise to a solution of N-sulfamyl-3-(methylthio)propionamidine (4.94 g, 25 mmol) in methanol (50 ml) at room temperature. After stirring for two hours, the product was collected by filtration, analytically pure, to give 4.44 g, mp 141°-144°.

Workup

  1. filtrationthe product was collected by filtration
  2. customanalytically pure, to give 4.44 g, mp 141°-144°

Sources & evidence

ORD record
ord-461e854f44064aca83215e2c4ef6b828
Source dataset
uspto-grants-1985_01
Patent number
US04496737

Linked notes

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