(Phenylthio)acetic acid → (Phenylthio)acetyl chloride

HRID 246816

Reaction equation

HRID 246816 reaction equation
[C:1]1([S:7][CH2:8][C:9]([OH:11])=O)[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.C(Cl)(=O)C([Cl:15])=O>C1(C)C=CC=CC=1>[C:1]1([S:7][CH2:8][C:9]([Cl:15])=[O:11])[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1

Participants

4

Reactant 2

HCID 59541(Phenylthio)acetic acidHCID 65578Oxalyl chloride

Product 1

HCID 4063350(Phenylthio)acetyl chloride

Reagents, catalysts & solvents 1

HCID 1140TolueneSolvent

Procedure

To a solution of 5.0 g of (phenylthio)acetic acid in 20 ml of toluene under nitrogen was added 5.2 ml of oxalyl chloride in four portions. The solution was stirred at room temperature for about twenty hours and then concentrated in vacuo to the oily title compound, which was used in subsequent reactions without further purificaton or characterization.

Workup

  1. concentrationconcentrated in vacuo to the oily title compound, which

Sources & evidence

ORD record
ord-9ef97c2bf9824e38b8c136f32ff6aa57
Source dataset
uspto-grants-1987_11
Patent number
US04704386

Linked notes

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