Ethylene carbonate → Ethylene carbonate

HRID 247716

Reaction equation

HRID 247716 reaction equation
[C:1]1(=[O:6])[O:5][CH2:4][CH2:3][O:2]1.CC(N)COCC(OCC(OCC(N)C)C)C>O.O.O.[O-][Sn]([O-])=O.[Na+].[Na+]>[C:1]1(=[O:6])[O:5][CH2:4][CH2:3][O:2]1.[C:1](=[O:5])=[O:2]

Participants

5

Reactant 2

HCID 7303Ethylene carbonateHCID 15131492Jeffamine

Product 2

HCID 280Carbon DioxideYield 11.1%HCID 7303Ethylene carbonateYield 96%

Reagents, catalysts & solvents 1

HCID 21977542Sodium StannateCatalyst

Conditions

Temperature
135 °C

Procedure

A 10:1 mole ratio of ethylene carbonate to aminated poly(propylene glycol) (Jeffamine D-400, Mw=430, a product of the Jefferson Chemical Division of Texaco) is heated with stirring under a nitrogen atmosphere for 19 hours at 135° C. using 0.5 percent sodium stannate trihydrate as catalyst to give 96 percent ethylene carbonate conversion to a poly(alkylene carbonate) polyol with 11.1 percent carbon dioxide. The catalyst is removed in Example 1.

Sources & evidence

ORD record
ord-3f5818ac9ab54d41a134f1ff0c2dba2a
Source dataset
uspto-grants-1987_11
Patent number
US04709069

Linked notes

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