1-Chlorooctane → Octyltin trichloride

Reaction equation

C([Sn:9]([Cl:19])([Cl:18])[CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH3:17])CCCCCCC.C([Cl:28])CCCCCCC.[Cl-].C[S+](C)C>>[CH2:10]([Sn:9]([Cl:18])([Cl:19])[Cl:28])[CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH3:17]

Participants

Reactant 3

HCID 81421-Chlorooctane

HCID 77080Dioctyltin dichloride

HCID 10176118Trimethylsulfonium chloride

Product 1

HCID 76538Octyltin trichloride

Procedure

Following the procedure outlined in Example 1, except that di-n-octyltin dichloride is used in place of dimethyltin dichloride, n-octyl chloride in place of methyl chloride, and trimethylsulfonium chloride in place of trimethylsulfonium iodide, there is obtained n-octyltin trichloride.

Sources & evidence

ORD record: ord-960cb227f83d48109f56fbfe1f9e7197
Source dataset: uspto-grants-1979_04
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US04148814

Reaction notes

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