Sodium Iodide → HCID 178502576, compound

HRID 267645

Reaction equation

HRID 267645 reaction equation
[CH3:1][O:2][C:3]([P:5](=[O:12])([O:9][CH2:10][CH3:11])[O:6]CC)=[O:4].[I-].[Na+:14]>O1CCCC1>[CH3:1][O:2][C:3]([P:5](=[O:6])([OH:12])[OH:9])=[O:4].[CH2:10]([Na:14])[CH3:11]

Participants

4

Reactant 2

HCID 5238Sodium IodideHCID 170573Phosphinecarboxylic acid, 1,1-diethoxy-, methyl ester, 1-oxide

Product 1

HCID 178502576HCID 178502576, compound

Reagents, catalysts & solvents 1

HCID 8028TetrahydrofuranSolvent

Procedure

A solution of 5.9 parts of diethyl methoxycarbonylphosphonate and 4.5 parts of sodium iodide was stirred at room temperature in 50 parts of tetrahydrofuran for 60 hours. The resulting mixture was filtered to give 3.5 parts of the desired ethyl sodium methoxycarbonylphosphonate, m.p. 123°d.

Workup

  1. filtrationThe resulting mixture was filtered

Sources & evidence

ORD record
ord-06455ecc7d1146709419d5a44461d24b
Source dataset
uspto-grants-1976_03
Patent number
US03943201

Linked notes

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