Hydroxylamine → p-Chlorobenzylmercaptoacetohydroxamic acid

HRID 26798

Reaction equation

HRID 26798 reaction equation
[Cl:1][C:2]1[CH:14]=[CH:13][C:5]([CH2:6][S:7][CH2:8][C:9](OC)=[O:10])=[CH:4][CH:3]=1.[NH2:15][OH:16].CO[Na]>CO>[Cl:1][C:2]1[CH:14]=[CH:13][C:5]([CH2:6][S:7][CH2:8][C:9]([NH:15][OH:16])=[O:10])=[CH:4][CH:3]=1

Participants

5

Reactant 3

HCID 787HydroxylamineHCID 3311340Methyl 2-(4-chlorobenzylthio)acetateHCID 178418582HCID 178418582, compound

Product 1

HCID 54399917p-Chlorobenzylmercaptoacetohydroxamic acid

Reagents, catalysts & solvents 1

HCID 887MethanolSolvent2×

Procedure

A solution of 0.15 mol of methyl p-chlorobenzylmercapto-acetate in 50 ml of methanol is mixed with a solution of 0.225 mol of hydroxylamine (base) and 0.15 mol of CH3ONa in 150 ml of methanol.

Sources & evidence

ORD record
ord-efaa9b4c7b1c4dcb9527ca58e78e2040
Source dataset
uspto-grants-1979_04
Patent number
US04151300

Linked notes

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