Acrylamide → Prop-2-enimidic acid--2-(dimethylamino)ethyl 2-methylprop-2-enoate (1/1)

HRID 27830

Reaction equation

HRID 27830 reaction equation
[CH3:1][C:2]([C:4]([O:6][CH2:7][CH2:8][N:9]([CH3:11])[CH3:10])=[O:5])=[CH2:3].[C:12]([NH2:16])(=[O:15])[CH:13]=[CH2:14]>>[C:12]([NH2:16])(=[O:15])[CH:13]=[CH2:14].[CH3:3][C:2]([C:4]([O:6][CH2:7][CH2:8][N:9]([CH3:11])[CH3:10])=[O:5])=[CH2:1]

Participants

3

Reactant 2

HCID 6579AcrylamideHCID 17869(Dimethylamino)ethyl methacrylate2×

Product 1

HCID 160008Prop-2-enimidic acid--2-(dimethylamino)ethyl 2-methylprop-2-enoate (1/1)

Procedure

As can be seen from the Table, after 7 hours g.l.c. shows only 3.5% residual DMAEMA but 35.7% acrylamide, indicating an approximate quat content of 35% (based on the DMAEMA in the copolymer). The percentage quaternization as determined by g.l.c. is generally in good agreement with the values obtained on similar systems by Nmr analysis.

Workup

  1. customobtained on similar systems by Nmr analysis

Sources & evidence

ORD record
ord-ed0fc6d719ec4c2e9a33401709d5c892
Source dataset
uspto-grants-1980_09
Patent number
US04224150

Linked notes

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