4-Toluenesulfonyl chloride → 9-Tosyloxymethyl-9,10-dihydro-9,10-methanoanthracene

HRID 27947

Reaction equation

HRID 27947 reaction equation
[OH:1][CH2:2][C:3]12[CH2:17][CH:10]([C:11]3[CH:12]=[CH:13][CH:14]=[CH:15][C:16]=31)[C:9]1[C:4]2=[CH:5][CH:6]=[CH:7][CH:8]=1.[C:18]1([CH3:28])[CH:23]=[CH:22][C:21]([S:24](Cl)(=[O:26])=[O:25])=[CH:20][CH:19]=1>>[S:24]([O:1][CH2:2][C:3]12[CH2:17][CH:10]([C:9]3[CH:8]=[CH:7][CH:6]=[CH:5][C:4]=31)[C:11]1[C:16]2=[CH:15][CH:14]=[CH:13][CH:12]=1)([C:21]1[CH:22]=[CH:23][C:18]([CH3:28])=[CH:19][CH:20]=1)(=[O:26])=[O:25]

Participants

3

Reactant 2

HCID 73974-Toluenesulfonyl chlorideHCID 130690829-Hydroxymethyl-9,10-dihydro-9,10-methanoanthracene

Product 1

HCID 205199599-Tosyloxymethyl-9,10-dihydro-9,10-methanoanthracene

Procedure

9-Tosyloxymethyl-9,10-dihydro-9,10-methanoanthracene is prepared from 9-hydroxymethyl-9,10-dihydro-9,10-methanoanthracene by treatment with p-toluenesulfonyl chloride in the presence of a base in an inert solvent;

Sources & evidence

ORD record
ord-b23b7442e3d24c0e90ed04a708d3297d
Source dataset
uspto-grants-1980_09
Patent number
US04224344

Linked notes

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