Potassium Cation → (+/-)-2-(Azidomethyl)-7-(2-methoxyphenyl)-2,3-dihydro-1-benzofuran

HRID 290134

Reaction equation

HRID 290134 reaction equation
[C:34](=[O:35])([O-:36])[O-:37].[CH3:1][c:2]1[cH:3][cH:4][c:5]([S:6]([O:7][CH2:8][CH:9]2[CH2:10][c:11]3[cH:12][cH:13][cH:14][c:15]([Br:16])[c:17]3[O:18]2)(=[O:19])=[O:20])[cH:21][cH:22]1.[CH3:23][O:24][c:25]1[cH:26][cH:27][cH:28][cH:29][c:30]1[B:31]([OH:32])[OH:33].[CH3:40][c:41]1[cH:42][cH:43][c:44]([S:45]([O:46][CH2:51][CH:52]2[O:53][c:54]3[c:55]([cH:57][cH:58][cH:59][c:60]3-[c:61]3[c:62]([O:67][CH3:68])[cH:63][cH:64][cH:65][cH:66]3)[CH2:56]2)(=[O:47])=[O:48])[cH:49][cH:50]1.[K+:38].[K+:39].[N-:81]=[N+:82]=[N-:83].[Na+:80].[O-:69][S:70]([c:71]1[cH:72][cH:73][c:74]([CH3:75])[cH:76][cH:77]1)(=[O:78])=[O:79]>>[CH2:51]([CH:52]1[O:53][c:54]2[c:55]([cH:57][cH:58][cH:59][c:60]2-[c:61]2[c:62]([O:67][CH3:68])[cH:63][cH:64][cH:65][cH:66]2)[CH2:56]1)[N:81]=[N+:82]=[N-:83]

Participants

9

Reactant 8

HCID 813Potassium Cation2×HCID 923Sodium ionHCID 19660Carbonate IonHCID 33558AzideHCID 85570p-ToluenesulfonateHCID 27339582-Methoxyphenylboronic acidHCID 58747572(7-Bromo-2,3-dihydro-1-benzofuran-2-yl)methyl 4-methylbenzenesulfonateHCID 86599090(+)-[7-(2-Methoxyphenyl)-2,3-dihydro-1-benzofuran-2-yl]methyl 4-methylbenzenesulfonate

Product 1

HCID 86599203(+/-)-2-(Azidomethyl)-7-(2-methoxyphenyl)-2,3-dihydro-1-benzofuran

Sources & evidence

ORD record
ord-1119811baf2c45238ad2835c674d576f
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (8/10)

Linked notes

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