Ammonium → 9-Iodo-5-methoxycarbonylmethyl-6,7-dihydro-1H, 5H-pyrido[1,2,3-de]quinoxaline-2,3-dione

HRID 310795

Reaction equation

HRID 310795 reaction equation
[Br:1][c:2]1[cH:3][c:4]2[c:5]3[n:6]([c:7](=[O:13])[c:8](=[O:12])[nH:9][c:10]3[cH:11]1)[CH:14]([CH2:17][C:18](=[O:19])[O:20][CH3:21])[CH2:15][CH2:16]2.[CH3:27][N:28]([CH3:29])[P:30](=[O:31])([N:32]([CH3:33])[CH3:34])[N:35]([CH3:36])[CH3:37].[Cl-:25].[I-:23].[I-:24].[K+:22].[NH4+:26]>>[c:2]1([I:23])[cH:3][c:4]2[c:5]3[n:6]([c:7](=[O:13])[c:8](=[O:12])[nH:9][c:10]3[cH:11]1)[CH:14]([CH2:17][C:18](=[O:19])[O:20][CH3:21])[CH2:15][CH2:16]2

Participants

7

Reactant 6

HCID 223AmmoniumHCID 312ChlorideHCID 813Potassium CationHCID 12679HexamethylphosphoramideHCID 30165Iodide Ion2×HCID 10066635Methyl 2-(9-bromo-2,3-dioxo-2,3,6,7-tetrahydro-1H,5H-pyrido[1,2,3-de]quinoxalin-5-yl)acetate

Product 1

HCID 540727779-Iodo-5-methoxycarbonylmethyl-6,7-dihydro-1H, 5H-pyrido[1,2,3-de]quinoxaline-2,3-dione

Sources & evidence

ORD record
ord-5056effd0d304154b5cb00f54b850b93
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (8/10)

Linked notes

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