Perchlorate → Phenylphosphine

HRID 329829

Reaction equation

HRID 329829 reaction equation
C(=O)([O-])[O-].C[C:6]1([PH3+:12])[CH:11]=[CH:10][CH:9]=[CH:8][CH2:7]1.C[C:14]1([PH3+:20])C=CC=CC1.[Cl:21]([O-:25])(=[O:24])(=[O:23])=[O:22]>O>[C:6]1([PH2:12])[CH:11]=[CH:10][CH:9]=[CH:8][CH:7]=1.[Cl:21]([O-:25])(=[O:24])(=[O:23])=[O:22].[CH3:14][PH3+:20]

Participants

5

Reactant 2

HCID 123351PerchlorateHCID 867436591-Methylphenylphosphanium carbonate

Product 2

HCID 12519PhenylphosphineHCID 19871530Methylphosphanium perchlorate

Reagents, catalysts & solvents 1

HCID 962WaterSolvent

Procedure

By following the same procedure as the 2nd step of Example 12 except that 10.0 g of 1-methylphenylphosphanium carbonate, 6.9 g of 60% perchlorate, and 10.0 g of water were used, 10.9 g (94.8% of the theoretical yield, yield of 67.6% to 1-phenylphosphane) of methylphosphanium perchlorate was obtained.

Sources & evidence

ORD record
ord-f1dfed6d36574850a6245e0f377c767f
Source dataset
uspto-grants-1990_01
Patent number
US04892944

Linked notes

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