Hydrochloric Acid → HCID 178511167, compound

HRID 330214

Reaction equation

HRID 330214 reaction equation
[P:1]([OH:4])([OH:3])[OH:2].Cl.[NH2:6][CH2:7][CH2:8][CH:9]([CH2:11][NH2:12])[OH:10].C=O>>[PH:1](=[O:2])([OH:4])[OH:3].[NH2:6][CH2:7][CH2:8][CH:9]([CH2:11][NH2:12])[OH:10]

Participants

5

Reactant 4

HCID 313Hydrochloric AcidHCID 712Formaldehyde2×HCID 107909Phosphorous acidHCID 1646562-Hydroxyputrescine

Product 1

HCID 178511167HCID 178511167, compound

Procedure

To a 500 ml three neck flask fitted with a reflux condenser and dropping funnel is added 131.2 grams (1.12 moles) 70% phosphorous acid and 207.2 grams (2.1 moles) 37% hydrochloric acid. Aminoethyl ethanolamine, 42.1 grams (0.40 mole) is then added dropwise while stirring. The mixture is then heated to reflux and 97.3 grams (1.2 moles) 37% aqueous formaldehyde is added dropwise during 1 hour. Reflux is continued for 2 hours after completion of the formaldehyde addition. The mixture is then cooled and bottled.

Workup

  1. temperatureThe mixture is then heated
  2. temperatureto reflux
  3. temperatureReflux
  4. temperatureThe mixture is then cooled

Sources & evidence

ORD record
ord-f5e410aebe704cc896a775c07499a96a
Source dataset
uspto-grants-1990_01
Patent number
US04895600

Linked notes

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