Tristearin → Erucic Acid

HRID 342340

Reaction equation

HRID 342340 reaction equation
[CH3:1][CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][C:18]([O:20]CC([O:44][C:45]([CH2:47][CH2:48][CH2:49][CH2:50][CH2:51][CH2:52][CH2:53][CH2:54][CH2:55][CH2:56][CH2:57][CH2:58][CH2:59][CH2:60][CH2:61][CH2:62][CH3:63])=[O:46])COC(CCCCCCCCCCCCCCCCC)=O)=[O:19]>CC(C)=O>[C:45]([OH:44])(=[O:46])[CH2:47][CH2:48][CH2:49][CH2:50][CH2:51][CH2:52][CH2:53][CH2:54][CH2:55][CH2:56][CH2:57]/[CH:58]=[CH:59]\[CH2:60][CH2:61][CH2:62][CH2:63][CH2:1][CH2:2][CH2:3][CH3:4].[C:18]([OH:20])(=[O:19])[CH2:17][CH2:16][CH2:15][CH2:14][CH2:13][CH2:12][CH2:11]/[CH:10]=[CH:9]\[CH2:8][CH2:7][CH2:6][CH2:5][CH2:4][CH2:3][CH2:2][CH3:1]

Participants

4

Reactant 1

HCID 11146Tristearin3×

Product 2

HCID 445639Oleic AcidYield 30%HCID 5281116Erucic AcidYield 62%

Reagents, catalysts & solvents 1

HCID 180AcetoneSolvent

Procedure

A spread was prepared in a manner similar as described in Example I, except that the mixture to be interesterified comprised 57 parts of the palm oil stearin and 43 parts of the palmkernel stearin. The margarine fat blend comprised 8% of the stearin fraction obtained from fractionation in acetone of the randomly interesterified mixture, 62% low erucic acid rapeseed oil and 30% of a high oleic acid residue containing variety of linseed oil. A very good product was obtained.

Workup

  1. customA spread was prepared in a manner similar

Sources & evidence

ORD record
ord-c3acdc9d01fa46238449b3d3c0b1fee6
Source dataset
uspto-grants-1999_01
Patent number
US05858445

Linked notes

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