Benzenamine, 2-phenoxy- → 1-Isothiocyanato-2-phenoxybenzene

HRID 349384

Reaction equation

HRID 349384 reaction equation
[C:1](C1NC=CN=1)(C1NC=CN=1)=[S:2].[O:13]([C:20]1[CH:26]=[CH:25][CH:24]=[CH:23][C:21]=1[NH2:22])[C:14]1[CH:19]=[CH:18][CH:17]=[CH:16][CH:15]=1>C1COCC1>[O:13]([C:20]1[CH:26]=[CH:25][CH:24]=[CH:23][C:21]=1[N:22]=[C:1]=[S:2])[C:14]1[CH:15]=[CH:16][CH:17]=[CH:18][CH:19]=1

Participants

4

Reactant 2

HCID 75899Benzenamine, 2-phenoxy-HCID 11412697Thiocarbonyl diimidazole

Product 1

HCID 220404391-Isothiocyanato-2-phenoxybenzene

Reagents, catalysts & solvents 1

HCID 8028TetrahydrofuranSolvent

Procedure

1.96 g (0.011 mol) of thiocarbonyl diimidazole were added to a solution of 1.85 g (0.01 mol) of 2-phenoxyaniline in 50 ml of THF and the mixture was stirred at room temperature for 4 hours, giving, after removal of the solvent by distillation, the compound as a brown amorphous product.

Workup

  1. customgiving
  2. customafter removal of the solvent
  3. distillationby distillation

Sources & evidence

ORD record
ord-853bee71781a42c6a85dc3d3c78adb8d
Source dataset
uspto-grants-2007_02
Patent number
US07179829B2

Linked notes

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