Chloroform → HCID 86744688, compound

HRID 360004

Reaction equation

HRID 360004 reaction equation
C(Cl)(Cl)Cl.[C:5]([OH:33])(=[O:32])[CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][C:14]#[C:15][C:16]#[C:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH2:29][CH2:30][CH3:31].[Cl-].[Cd+2:35].[Cl-].C(=O)(O)[O-].[K+]>O>[C:5]([O-:33])(=[O:32])[CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][C:14]#[C:15][C:16]#[C:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH2:29][CH2:30][CH3:31].[Cd+2:35].[C:5]([O-:33])(=[O:32])[CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][C:14]#[C:15][C:16]#[C:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH2:29][CH2:30][CH3:31]

Participants

6

Reactant 4

HCID 6212ChloroformHCID 24633Cadmium chloride, dihydrateHCID 516893Potassium BicarbonateHCID 2006470510,12-Heptacosadiynoic Acid

Product 1

HCID 86744688HCID 86744688, compound

Reagents, catalysts & solvents 1

HCID 962WaterSolvent

Procedure

A chloroform solution of heptacosa-10,12-diynoic acid was allowed to spread over the surface of a water solution of 4×10-4M cadmium chloride and 5×10-5M potassium bicarbonate; the solvent was then evaporated and the surface pressure is raised to 10 mN/m, thus forming a film of cadmium heptacosa-10,12-diynoate on the surface of the water. The Langmuir-Blodgett method was used to laminate 11 layers of this film onto a glass substrate, the surface of which had been treated to be hydrophilic.

Workup

  1. customthe solvent was then evaporated
  2. temperaturethe surface pressure is raised to 10 mN/m

Sources & evidence

ORD record
ord-b510c1674da346309035686367a27915
Source dataset
uspto-grants-1991_03
Patent number
US05003569

Linked notes

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