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Cadmium chloride, dihydrate

HCID 24633
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Basic informationOverviewNames & identifiersPropertiesSafety & regulationChemistry & industryRelated reactionsCompound notes
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Basic information

CAS
10108-64-2
Standard SMILES
[Cd+2].[Cl-].[Cl-]
InChIKey
YKYOUMDCQGMQQO-UHFFFAOYSA-L
Molecular formula
CdCl2
Average molar mass
183.32 g/mol
Monoisotopic mass
183.84106386

Overview

See also: Cadmium Chloride (preferred).

Names & identifiers

Preferred name
Cadmium chloride, dihydrate
IUPAC
cadmium(2+) dichloride
English name
Cadmium chloride
Molecular formula
CdCl2
Molecular weight
183.32

Names & synonyms

CADMIUM CHLORIDE, DIHYDRATEcadmium(2+);dichlorideCAS-10108-64-273664-99-0109-Cadmium chlorideCadmium chloride (CdCl)(109Cd)Cadmium chloridecadmium(II)chlorideSCHEMBL19856CADMIUM CHLORIDE [MI]CADMIUM CHLORIDE [HSDB]CADMIUM MURIATICUM [HPUS]
Show more names
CdCl2Cadmium chloride (CdCl2)cadmium chloride solutionCaddyVi-CadNSC 51148KadmiumchloridDichlorocadmiumCADMIUM CHLORIDECadmium dichloride
CADMIUM CHLORIDE [WHO-DD]Tox21_202229Tox21_303000AKOS024256118NCGC00090932-01NCGC00256542-01NCGC00259778-0113966-86-4

Database identifiers

CAS
10108-64-2、13966-86-4、72589-96-9、73664-99-0
PubChem CID
24633
DTXSID
DTXSID6020226
UNII
J6K4F9V3BA
Nikkaji
J3.116J

Properties

Computed structural properties

Topological polar surface area
0 Ų
Hydrogen bond donors
0
Hydrogen bond acceptors
2
Rotatable bonds
0
Heavy atoms
3
Formal charge
0
Complexity
0

Experimental & physicochemical properties

Endocrine DisruptorsPotential endocrine disrupting compound

Physicochemical properties

Melting point
568 °C · 568 °C(lit.)
Boiling point
960 °C · 960 °C
Density
1.01 g/mL · 1.01 g/mL at 20 °C
vapor density
6.3 · 6.3 (vs air)
vapor pressure
10 mm · 10 mm Hg ( 656 °C)
Flash point
960 °C · 960°C
storage temp.
2 · 2-8°C
solubility
2 O: · H2O: soluble
form
beads
color
White
Specific Gravity
4.047 · 4.047
Odor
Odorless
Water Solubility
1400 g/L · 1400 g/L (20 ºC)
Specific Heat Capacity
0.41 J/ · Cp(crystal): 0.41 J/(g·K), at 25℃

Safety & regulation

Safety information is for reference only and does not replace the supplier’s Safety Data Sheet (SDS), applicable regulations, or professional assessment.

Safety data

F
3-9-23
PPE
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
wgk
3
tsca
TSCA listed
rtecs
EV0175000
ridadr
UN 3082 9/PG 3
hs_code
28273985
Toxicity
LD50 orally in rats: 88 mg/kg (Nriagu)
risk_code
45-46-60-61-25-26-48/23/25-51/53-50/53-48/20/22-23-22
Signal word
Danger
Symbol(GHS)
GHS06,GHS08,GHS09
hazard_code
T,N,T+
safety_code
53-45-61-60-36/37-28
hazard_class
6.1
Storage Class
6.1A - Combustible acute toxic Cat. 1 and 2very toxic hazardous materials
packing_group
III
Hazard statements
H330-H301-H360-H372-H370-H340-H350-H410
Limited Quantities
5.0 L (1.3 gallons) (liquid) or 5.0 kg (11 lbs) (solid)
Excepted Quantities
Max Inner Pack (30g or 30ml) and Max Outer Pack (1Kg or 1L)
REACH Registrations
Active
Hazard Classifications
Acute Tox. 2 InhalationAcute Tox. 3 OralAquatic Acute 1Aquatic Chronic 1Carc. 1BMuta. 1BRepr. 1BSTOT RE 1
Precautionary statements
P501-P273-P260-P270-P202-P201-P271-P264-P280-P284-P391-P308+P311-P301+P310+P330-P304+P340+P310-P403+P233-P405
Hazardous Substances Data

Chemistry & industry

Applications · 8 items

DescriptionCadmium chloride is a cadium halide consisting of cadmium and chlorine. It is well soluble in water, methanol and ethanol. It can be used in photography, in dyeing, electroplating fabric printing and calico printing and for precipitating sulfide. It can be used for the manufacture of cadium sulfide, organocadium compound of the type R2Cd. It is manufactured through the reaction between anhydrous chlorine and hydrogen chloride gas with heated cadmium metal. It can also be made through the reaction between hydrochloric acid with cadmium oxide. However, it is a hazard to the environment, and should be limited for spread.

UsesCadmium chloride (CdCl2), a soluble crystal, is formed when cadmium metal is treated with hydrochloric acid (Cd + 2HCl → CdCl2 + H2). CdCl2 is used in dyeing and printing textiles, in electroplating baths, in photography, and as the ingredient for cadmium yellow in artists’ oil paint.

DescriptionCadmium chloride is a colourless and odourless crystal. It is used for the preparation of cadmium sulphide, used as ‘cadmium yellow’, a brilliant-yellow pigment, which is stable to heat and sulphide fumes. Cadmium chloride has a high solubility in water and is a non-combustible solid, but the dust can be a moderate fire hazard when exposed to heat or flame or when reacted with oxidising agents. It is incompatible with bromine trifluoride, potassium oxidisers, zinc, selenium, tellurium, and hydrogen azide.

UsesMade by the action of hydrochloric acid on cadmium and crystallization. The small white crystals are soluble in alcohol and water. Cadmium chloride was used to make collodionchloride printing-out emulsions, also known as leptographic or aristotype papers.

UsesUsed in a preparation of highly luminescent CdTe nanocrystals.1

UsesCadmium Chloride is used in the preparation of the stable inorganic pigment cadmium sulfide (Cadmium Yellow). Cadmium Chloride treatment of thin film CDTe solar cells is used to produce high-efficienc y solar cells.. Cadmium Chloride is also used in the preparation of organocadmium compounds.

UsesPreparation of cadmium standard; analysis of sulfides; testing of pyridine bases.

General DescriptionCadmium chloride is a white crystalline solid. Cadmium chloride is soluble in water. Cadmium chloride is noncombustible. The primary hazard of Cadmium chloride is that Cadmium chloride poses a threat to the environment. Immediate steps should be taken to limit its spread to the environment. Cadmium chloride is used in photography, in fabric printing, in chemical analysis, and in many other uses.

Related reactions

28 records
New reaction record
HRID 26358 reaction equation
HRID 26358As reactantuspto-grants-1979_04
HRID 66080 reaction equation
HRID 66080As catalystuspto-grants-1978_12
HRID 244381 reaction equation
HRID 244381As catalystuspto-grants-2014_02
HRID 360004 reaction equation
HRID 360004As reactantuspto-grants-1991_03
HRID 394465 reaction equation
HRID 394465As reactantuspto-grants-2003_08
HRID 434308 reaction equation
HRID 434308As reactantuspto-grants-1983_08
HRID 436930 reaction equation
HRID 436930As catalystuspto-grants-1977_06
HRID 463512 reaction equation
HRID 463512As catalystuspto-grants-1985_05
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Compound notes

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Crystal Structure
2 type · CdCl2 type
Sensitive
Hygroscopic
Merck
14 · 14,1617
crystal system
Three sides
Space group
3 m · R3m
Lattice constant
a/nm
Symbol(GHS)
6 · GHS06,GHS08,GHS09
Signal word
Danger
Hazard statements
330 · H330-H301-H360-H372-H370-H340-H350-H410
Precautionary statements
501 · P501-P273-P260-P270-P202-P201-P271-P264-P280-P284-P391-P308+P311-P301+P310+P330-P304+P340+P310-P403+P233-P405
PPE
3 · Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
Hazard Codes
T,N,T+
Risk Statements
45 · 45-46-60-61-25-26-48/23/25-51/53-50/53-48/20/22-23-22
Safety Statements
53 · 53-45-61-60-36/37-28
RIDADR
3082 · UN 3082 9/PG 3
WGK Germany
3 · 3
RTECS
175000 · EV0175000
F
3 · 3-9-23
TSCA
TSCA listed
HazardClass
6.1 · 6.1
PackingGroup
III
HS Code
28273985 · 28273985
Storage Class
6.1 A · 6.1A - Combustible acute toxic Cat. 1 and 2very toxic hazardous materials
Hazard Classifications
2 InhalationAcute · Acute Tox. 2 InhalationAcute Tox. 3 OralAquatic Acute 1Aquatic Chronic 1Carc. 1BMuta. 1BRepr. 1BSTOT RE 1
Hazardous Substances Data
10108 · 10108-64-2(Hazardous Substances Data)
Toxicity
50 orally · LD50 orally in rats: 88 mg/kg (Nriagu)
REACH Registrations
Active
Limited Quantities
5 L · 5.0 L (1.3 gallons) (liquid) or 5.0 kg (11 lbs) (solid)
Excepted Quantities
Max Inner Pack (30g or 30ml) and Max Outer Pack (1Kg or 1L)
10108-64-2(Hazardous Substances Data)
Preparation methods · 1 item

PreparationCadmium chloride may be prepared by heating the metal with chlorine or hydrogen chloride gas. In the solution, it is formed by treating the metal or its salts, such as oxide, hydroxide, carbonate, or sulfide with hydrochloric acid:Cd + 2HCl → CdCl2 + H2CdO + 2HCl → CdCl2 + H2OCdCO3 + 2HCl → CdCl2+ H2O + CO2The solution is evaporated and crystallized to yield a hydrated salt. The hydrated salt yields anhydrous cadmium chloride upon heating under hydrogen chloride or when refluxed with thionyl chloride.Cadmium chloride also may be prepared by adding dry cadmium acetate to acetyl chloride in glacial acetic acid.

Upstream & downstream products

Upstream raw materials

Hydrochloric acidCADMIUM

Downstream products

3-Methyl-2-pentanoneCadmium chloride hemi(pentahydrate)Cadmium carbonatedichlorine oxideSeleniumDimethylcadmiumCadmium stearatecadmium bis[benzoate]cadmium bis(piperidine-1-carbodithioate)

Additional notes

DefinitionChEBI: Cadmium dichloride is a cadmium coordination entity in which cadmium(2+) and Cl(-) ions are present in the ratio 2:1. Although considered to be ionic, it has considerable covalent character to its bonding.