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Hydrochloric Acid → (2-Chloro-2-phenylethyl)benzene

HRID 363999
Notes
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Reaction equation

HRID 363999 reaction equation
[CH2:1]=[CH:2][C:3]1[CH:8]=[CH:7][CH:6]=[CH:5][CH:4]=1.N[C:10]1[CH:15]=[CH:14][CH:13]=[CH:12][CH:11]=1.[ClH:16]>C(#N)C>[Cl:16][CH:1]([C:10]1[CH:15]=[CH:14][CH:13]=[CH:12][CH:11]=1)[CH2:2][C:3]1[CH:8]=[CH:7][CH:6]=[CH:5][CH:4]=1
ParticipantsProcedureSources & evidenceReaction notes

Participants

5

Reactant 3

HCID 313Hydrochloric AcidHCID 6115AnilineHCID 7501Styrene

Product 1

HCID 20838(2-Chloro-2-phenylethyl)benzeneYield 66.7%

Reagents, catalysts & solvents 1

HCID 6342AcetonitrileSolvent

Procedure

Following the general procedure of Example I, 236 mmols of distilled styrene were reacted with 25 mmols of distilled aniline in 30 mL of acetonitrile and in the presence of 38 mmols of concentrated HCl and 2.5 mmols of cuprous oxide. The process resulted in a 66.7% yield of 2-chloro-1,2-diphenylethane.

Sources & evidence

ORD record
ord-d3ce35c9bc77492786108201bebe8de5
Source dataset
uspto-grants-1986_08
DOI
10.6084/m9.figshare.5104873.v1
Patent number
US04604243

Reaction notes

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On this pageParticipantsProcedureSources & evidenceReaction notes