p-n-Octadecyloxybenzoic acid → HCID 18521013, compound

HRID 369537

Reaction equation

HRID 369537 reaction equation
O.[OH-].[Li+].[CH2:4]([O:22][C:23]1[CH:31]=[CH:30][C:26]([C:27]([OH:29])=[O:28])=[CH:25][CH:24]=1)[CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13]CCCCCCCC>CO>[CH2:4]([O:22][C:23]1[CH:24]=[CH:25][C:26]([C:27]([OH:29])=[O:28])=[CH:30][CH:31]=1)/[CH:5]=[CH:6]/[CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH3:13]

Participants

4

Reactant 2

HCID 139993p-n-Octadecyloxybenzoic acidHCID 168937Lithium hydroxide, monohydrate

Product 1

HCID 18521013HCID 18521013, compound

Reagents, catalysts & solvents 1

HCID 887MethanolSolvent

Procedure

The ester 35 g 565 mg, 1.95 mmol), and lithium hydroxide monohydrate (817 mg, 19.5 mmol) in 20 ml methanol were reacted according to the procedure for compound 36a. The yield was 482 mg (89% of a white powder.

Sources & evidence

ORD record
ord-4f99fb4124484d709c27fecd5c085d15
Source dataset
uspto-grants-2000_10
Patent number
US06139771

Linked notes

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