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Gold → Gold Sulfite

HRID 372628
Notes
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Reaction equation

HRID 372628 reaction equation
[S:1]([O-:4])([O-:3])=[O:2].[Au+3:5].[Na+].[S:7]([O-:10])([O-:9])=[O:8].[S:11]([O-:14])([O-:13])=[O:12].[Na+].[Na+].[As].[Au]>[Cd]>[S:1]([O-:4])([O-:3])=[O:2].[Au+3:5].[S:7]([O-:10])([O-:9])=[O:8].[S:11]([O-:14])([O-:13])=[O:12].[Au+3:5]
ParticipantsProcedureWorkupSources & evidenceReaction notes

Participants

6

Reactant 4

HCID 23985GoldHCID 24437Sodium SulfiteHCID 5359596ArsenicHCID 6455600Gold(3+) pentasodium tetrasulphite

Product 1

HCID 86735730Gold Sulfite

Reagents, catalysts & solvents 1

HCID 23973CadmiumCatalyst

Procedure

A typical sulfite electroplating bath is an aqueous solution including sodium gold sulfite, about 5 to 10 troy ounces per gallon (41.1 to 82.2 grams per liter) of sodium sulfite, and brighteners such as arsenic or cadmium metal in amounts up to about 500 ppm. The aqueous solution usually has a pH of 8 to 12 and contains between one-quarter to 3 troy ounces per gallon (2.1 to 24.7 grams per liter) of gold.

Workup

  1. customA typical sulfite electroplating bath is

Sources & evidence

ORD record
ord-af3fc463b6df4498b7cc3c5d9a9db7ac
Source dataset
uspto-grants-1978_05
DOI
10.6084/m9.figshare.5104873.v1
Patent number
US04092154

Reaction notes

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On this pageParticipantsProcedureWorkupSources & evidenceReaction notes