Allyl Alcohol → Allyl Alcohol Allyl Acetate
Reaction equation
[CH2:1]([OH:4])[CH:2]=[CH2:3].[C:5]([O:8][CH2:9][CH:10]=[CH2:11])(=[O:7])[CH3:6].C(OOC(C)(C)C)(C)(C)C>>[CH2:1]([OH:4])[CH:2]=[CH2:3].[C:5]([O:8][CH2:9][CH:10]=[CH2:11])(=[O:7])[CH3:6]Participants
4
Conditions
- Temperature
- 150 °C
Procedure
The procedure of Example 1 is generally followed. The reactor is initially charged with allyl alcohol (200 g), allyl acetate (200 g), and di-tert-butylperoxide (10 g). After heating the reactor contents to 150° C., the remaining di-tertbutylperoxide (40 g) is added to the reactor continuously over 2.5 h. Heating continues for an additional 2 h at 150° C. After vacuum stripping as described above, the product (166 g) is isolated and characterized. The yield obtained is 42% based on the weight of charged monomers. Gel permeation chromatography (GPC) results: Mw=1081, Mn=708, Mw/Mn=1.52. By 13C NMR, the product contains 57 mole % of allyl alcohol recurring units, and 43 mole % of allyl acetate recurring units.