Methyl Acrylate → Dimethyl 2,2-dichloroglutarate

Reaction equation

[Cl:1][CH:2]([Cl:7])[C:3]([O:5][CH3:6])=[O:4].[CH3:8][O:9][C:10](=[O:13])[CH:11]=[CH2:12].C[O-].[Na+]>>[Cl:1][C:2]([Cl:7])([CH2:12][CH2:11][C:10]([O:9][CH3:8])=[O:13])[C:3]([O:5][CH3:6])=[O:4]

Participants

Reactant 3

HCID 7294Methyl Acrylate

HCID 8315Methyl dichloroacetate

HCID 10942334Sodium Methoxide

Product 1

HCID 12586444Dimethyl 2,2-dichloroglutarate

Procedure

reacting methyl dichloroacetate and acrylic acid methyl ester with sodium methoxide to obtain dimethyl 2,2-dichloroglutarate;

Sources & evidence

ORD record: ord-2a28b64d4eec407a8d30ac9cb3af3d7d
Source dataset: uspto-grants-2014_06
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US08754256B2

Reaction notes

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