p-n-Octadecyloxybenzoic acid → HCID 18521013, compound

HRID 413634

Reaction equation

HRID 413634 reaction equation
C[O:2][C:3](=[O:21])[C:4]1[CH:9]=[CH:8][C:7]([O:10][CH2:11]/[CH:12]=[CH:13]/[CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH3:20])=[CH:6][CH:5]=1.O.[OH-].[Li+].C(OC1C=CC(C(O)=O)=CC=1)CCCCCCCCCCCCCCCCC>CO>[CH2:11]([O:10][C:7]1[CH:6]=[CH:5][C:4]([C:3]([OH:21])=[O:2])=[CH:9][CH:8]=1)/[CH:12]=[CH:13]/[CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH3:20]

Participants

5

Reactant 3

HCID 139993p-n-Octadecyloxybenzoic acidHCID 168937Lithium hydroxide, monohydrateHCID 18521070Methyl-4-(trans-2-decenyloxy)-benzoate

Product 1

HCID 18521013HCID 18521013, compound

Reagents, catalysts & solvents 1

HCID 887MethanolSolvent

Procedure

The ester 35g 565 mg, 1.95 mmol), and lithium hydroxide monohydrate (817 mg, 19.5 mmol) in 20 ml methanol were reacted according to the procedure for compound 36a. The yield was 482 mg (89% of a white powder.

Sources & evidence

ORD record
ord-ccede109ff2a4b66956b2756cfc70ce9
Source dataset
uspto-grants-2003_05
Patent number
US06569504B1

Linked notes

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