Dimethyl Sulfide → Trimethylsulfonium Triflate
Reaction equation
[CH3:1][S:2][CH3:3].[CH3:4][O:5][S:6]([C:9]([F:12])([F:11])[F:10])(=[O:8])=[O:7]>ClCCl>[O-:8][S:6]([C:9]([F:12])([F:11])[F:10])(=[O:7])=[O:5].[CH3:1][S+:2]([CH3:4])[CH3:3]Participants
4
Reactant 2
Product 1
Reagents, catalysts & solvents 1
Procedure
16 mmol of dimethyl sulfide was dissolved in 10 ml of dichloromethane at 0° C., and about 17 mmol of methyltrifluoromethane sulfonate was slowly dripped to the mixture to obtain a white solid product. The solid product was filtered and dried for 1 hour in an oven at 50° C. to obtain the following product:
Workup
- customto obtain a white solid product
- filtrationThe solid product was filtered
- customdried for 1 hour in an oven at 50° C.
- customto obtain the following product
Sources & evidence
- ORD record
- ord-5cc9413dfef7447db1b13d03a866a5a8
- Source dataset
- uspto-grants-2013_09
- Patent number
- US08536347B2
Reaction notes
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