O-Cresol → 2,6-Dimethylphenol

HRID 435218

Reaction equation

HRID 435218 reaction equation
[C:1]1([CH3:8])[C:6]([OH:7])=[CH:5][CH:4]=[CH:3][CH:2]=1.[C:9]1(O)C=CC=CC=1.COC.[Si]=O.[O-2].[Ba+2]>[O-2].[Fe+2].[O-2].[V+5].[O-2].[O-2].[O-2].[O-2].[V+5].O>[C:6]1([OH:7])[C:5]([CH3:9])=[CH:4][CH:3]=[CH:2][C:1]=1[CH3:8]

Participants

9

Reactant 5

HCID 335O-CresolHCID 996PhenolHCID 8254Dimethyl EtherHCID 66241Silicon oxide (SiO)HCID 9855530Barium Oxide Nanoparticle Dispersion

Product 1

HCID 113352,6-Dimethylphenol

Reagents, catalysts & solvents 3

HCID 449809Ferrous oxideCatalystHCID 178419084HCID 178419084, compoundCatalystHCID 962WaterSolvent

Procedure

A mixture of o-cresol and phenol, dimethyl ether and water in a molar ratio of 1:2:2.6 were reacted as described in Example 1. The catalyst contained iron oxide, vanadium oxide, silicon oxide and barium oxide in a molar ratio of 100:2:10:0.1. After working up, 2.6-xylenol was obtained with a selectivity of 99%.

Workup

  1. customwere reacted

Sources & evidence

ORD record
ord-0e577805cbc34edb9d3509a4195c1f30
Source dataset
uspto-grants-1983_08
Patent number
US04400557

Linked notes

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