Chlorotrimethylsilane → (Hexyloxy)trimethylsilane

HRID 463363

Reaction equation

HRID 463363 reaction equation
[CH2:1]([OH:7])[CH2:2][CH2:3][CH2:4][CH2:5][CH3:6].[CH3:8][Si:9]([CH3:12])([CH3:11])Cl.C[Si](C)(C)NCCN[Si](C)(C)C>ClCCl>[CH2:1]([O:7][Si:9]([CH3:12])([CH3:11])[CH3:8])[CH2:2][CH2:3][CH2:4][CH2:5][CH3:6]

Participants

5

Reactant 3

HCID 6397ChlorotrimethylsilaneHCID 81031-HexanolHCID 74569N,N'-Bis(trimethylsilyl)ethylenediamine

Product 1

HCID 519489(Hexyloxy)trimethylsilaneYield 59%

Reagents, catalysts & solvents 1

HCID 6344DichloromethaneSolvent

Procedure

To hexan-1-ol (5.1 g, 0.05 mole) in dichloromethane (50 ml) were added trimethylchlorosilane (1.81 g, 0.0166 mole) and N,N'-bis(trimethylsilyl)ethlenediamine (3.44 g, 0.0166 mole). The mixture was stirred under reflux for 30 minutes, filtered and the solvent removed. The residue, hexanoxytrimethylsilane, was obtained in 59% yield (5.15 g).

Workup

  1. temperatureunder reflux for 30 minutes
  2. filtrationfiltered
  3. customthe solvent removed

Sources & evidence

ORD record
ord-492d73126dca42c6956bc86f6ab2124b
Source dataset
uspto-grants-1985_05
Patent number
US04518787

Linked notes

Loading…