Linoleoyl chloride → 9,12-Octadecadienoyl chloride, (9Z,12Z)-

HRID 463751

Reaction equation

HRID 463751 reaction equation
[C:1]([Cl:20])(=[O:19])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8]/[CH:9]=[CH:10]\[CH2:11]/[CH:12]=[CH:13]\[CH2:14][CH2:15][CH2:16][CH2:17][CH3:18].C(Cl)(=O)CCCCCCC/C=C\C/C=C/CCCCC.C(Cl)(=O)CCCCCCC/C=C\C=C\CCCCCC.C(Cl)(=O)CCCCCCCC/C=C/C/C=C/CCCCC.C(Cl)(=O)CCCCCCCCC/C=C/C/C=C/CCCCC>>[C:1]([Cl:20])(=[O:19])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8]/[CH:9]=[CH:10]/[CH2:11]/[CH:12]=[CH:13]/[CH2:14][CH2:15][CH2:16][CH2:17][CH3:18]

Participants

6

Reactant 5

HCID 9817754Linoleoyl chlorideHCID 15168608HCID 15168608, compoundHCID 19973261HCID 19973261, compoundHCID 20265109HCID 20265109, compoundHCID 86740353HCID 86740353, compound

Product 1

HCID 53655789,12-Octadecadienoyl chloride, (9Z,12Z)-

Procedure

In the above example, (Z,Z)-9,12-octadecadienoyl chloride, (Z,E)-9,12-octadecadienoyl chloride, (Z,E)-9,11-octadecadienoyl chloride, (E,E)-10,13-nonadecadienoyl chloride, and (E,E)-11,14-cosadienoyl chloride are substituted, respectively, for (E,E)-9,12-octadecadienoyl chloride, thereby obtaining each respective N vanillyl-alkadienamide.

Sources & evidence

ORD record
ord-aa2593857fc24411b96535377d9a29b8
Source dataset
uspto-grants-1985_10
Patent number
US04544669

Linked notes

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